By Volume

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Initial Team (Vol. 1)

Character

Joined in
Firestar New Warriors (Vol. 1) #1
Justice New Warriors (Vol. 1) #1
Namorita New Warriors (Vol. 1) #1
Night Thrasher New Warriors (Vol. 1) #1
Nova New Warriors (Vol. 1) #1
Speedball New Warriors (Vol. 1) #1

New members (Vol. 1)
Silhouette New Warriors (Vol. 1) #14
Darkhawk New Warriors (Vol. 1) #22
Rage New Warriors (Vol. 1) #26
Hindsight Lad New Warriors (Vol. 1) #48
Bandit New Warriors (Vol. 1) #48
Dagger New Warriors (Vol. 1) #48
Turbo (Mickey) New Warriors (Vol. 1) #48
Turbo (Mike) New Warriors (Vol. 1) #48
Zero-G New Warriors (Vol. 1) #48
Speedball (Darrion Grobe) New Warriors (Vol. 1) #50
Scarlet Spider (Ben Riley) New Warriors (Vol. 1) #62
Helix New Warriors (Vol. 1) #68
Timeslip New Warriors (Vol. 1) #72

Interim recruits
Slapstick A flashback in Avengers: The Initiative #10
Ultra Girl A flashback in Avengers: The Initiative #10

New members (Vol. 2)
Aegis New Warriors (Vol. 2) #1
Bolt New Warriors (Vol. 2) #1

New members (Vol. 3)
Microbe New Warriors (Vol. 3) #1
Debrii New Warriors (Vol. 3) #4

New members (Vol. 4)
Wondra New Warriors (Vol. 4) #1
Blackwing New Warriors (Vol. 4) #1
Decibel New Warriors (Vol. 4) #1
Tempest New Warriors (Vol. 4) #1
Ripcord New Warriors (Vol. 4) #1
Skybolt New Warriors (Vol. 4) #1
Phaser New Warriors (Vol. 4) #1
Longstrike New Warriors (Vol. 4) #1
Renascence New Warriors (Vol. 4) #6

Dark Reign
Scarlet Spiders Avengers: The Initiative #21

New Warriors (Vol. 5)
Nova Nova Vol.6 #10
Scarlet Spider New Warriors Vol. 5 #1
Sun Girl New Warriors Vol. 5 #1
Haechi New Warriors Vol. 5 #2
Water Snake New Warriors Vol. 5 #1
Hummingbird New Warriors Vol. 5 #1

Support staff
Tai New Warriors (Vol. 1) #1
Chord New Warriors (Vol. 1) #1
Sprocket New Warriors (Vol. 1) #29
Grace New Warriors (Vol.4) #3
Kaz New Warriors (Vol.4) #3
Aja New Warriors (Vol.4) #10